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| Compound | 4-Chlorophenylboronic acid | ||||
|---|---|---|---|---|---|
| CAS No. | 1679-18-1 | Catalog No. | XMZX-W5882 | Brand | |
| Purity | 99% | Packing | 25kg/DRUMS | Grade | |
| Lead Time | 3Day (s) | Origin | Loading Port | China,Xiamen,Siming District | |
| Boiling Point | 295.4ºC |
|---|---|
| Stability | Stable under normal temperatures and pressures. |
| Storage Condition | Refrigerator (+4ºC) |
| Appearance & Physical State | White - off-white powder. |
| Water Solubility | 2.5 g/100 mL |
| Flash Point | 132.4ºC |
| Refractive Index | 1.557 |
| Density | 1.32g/cm3 |
| Melting Point | 284-289ºC |
| Vapor Pressure | 0.000693mmHg at 25°C |
Uses suzuki reaction
Uses 4-Chlorobenzeneboronic Acid is used as a catalyst for the preparation of 4-hydroxycoumarin derivatives which display antitrypanosomal and antioxidant properties. It is also used as a catalyst for the asymmetric borane reduction of electron-deficient ketones.
Uses
4-Chlorophenylboronic acid can be used as a reactant in:
Palladium-catalyzed direct arylation.
Cyclopalladation.
Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation.
Copper-mediated ligandless aerobic fluoroalkylation.
Pd-catalyzed arylative cyclization.
Ruthenium catalyzed direct arylation.
Ligand-free copper-catalyzed coupling reactions.
Regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions.
It can also be used to prepare:
Substituted diarylmethylidenefluorenes via Suzuki coupling reaction.
Baclofen lactam by Suzuki coupling of a pyrrolinyl tosylate, followed by hydrogenation reaction.
Palladium(II) thiocarboxamide complexes as Suzuki coupling catalysts.
Biaryls by Suzuki reactions of aryl chlorides, bromides, and iodides with arylboronic acids.
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